The course includes 9 weeks of instruction. It begins October 7 and ends December 16. There will be no instruction or assignments the week of November 25.
Week 1 – Ideal Gas Law (IGL) and the Kinetic Molecular Theory (KMT)
Boyle's Law, Charles' Law, Absolute Zero, Ideal Gas Law, IGL Applications,
Dalton's Law of Partial Pressures, Postulates of the KMT
Week 2 – Phase Transitions and Phase Equilibrium
Derivation of the IGL from KMT Postulates, Interpretation of the IGL and Deviations
from the IGL, Observations of Phase Transitions, Vapor Pressure and Dynamic
Equilibrium
Week 3 – Phase Equilibrium and Solutions
Vapor Pressure and Intermolecular Forces, Vapor Pressure of Solutions, Raoult's
Law, Boiling Point Elevation and Melting Point Depression, Osmotic Pressure
Week 4 – Reaction Rate Laws and Reaction Kinetics
Solubility, Equilibrium and Ksp; Defining and Measuring Rates of Reactions; The Rate Law; Temperature Dependence; Arrhenius Equation; Collision Theory; Mechanisms for Complex Reactions
Week 5 – Gas Reaction Equilibrium
and Equilibrium Constants
Equilibrium Constants for Gas Reactions; Dynamic Equilibrium and Rate Laws; Applications; Le Châtelier’s principle
Week 6 – Strengths of Acids; Buffers
Acid-base definitions; Strong and Weak Acids; Observation of Ka; pH; Calculation of pH for Weak Acids; Hydrolysis of Anions; Kb; Neutralization Reactions; TitrationsWeek 7 – Strengths of Acids; Buffers
Relationship of Acid Strength to Bond Energy and Anion Stability; Buffers
Week 8 – Second Law of Thermodynamics
Probability and Spontaneity; Absolute Entropy; Spontaneity and Heat Transfer; Second Law of Thermodynamics
Week 9 – Free Energy and Thermodynamic Equilibrium
Free Energy; Phase Equilibrium and Vapor Pressure; Reaction Equilibrium and Equilibrium Constants; Temperature Dependence